每周的 ISEF 获奖论文解析来了!今天小助手邀请有方导师点评 2017 年获奖课题,这篇论文的获奖学生是来自日本的团队,学科:Energy: Chemical
ISEF 获奖课题信息
摘要或概述 Abstract / Summary
In order to realize a sustainable society, artificial photosynthesis has been gaining attention and has been widely studied in recent years. This research focused on tantalum oxide, which can be used to catalyze the reduction of carbon dioxide.
In this study, it was found that tantalum oxide/tantalum plate responds to visible light, and this is a novel phenomenon.
The objective of this research was to investigate the mechanism of this phenomenon and to make tantalum oxide/tantalum plate with a high energy conversion efficiency. The study consisted of four experiments, as follows: (i) a tantalum plate was heat-treated while varying the time, temperature, and type of gas, (ii) the voltage and electric current were measured under optical irradiation, (iii) the wavelength dependence was checked using visible light, (iv) the electric potential of the conduction band was measured using a potentiostat, and the reduction of carbon dioxide to formic acid by tantalum oxide/tantalum plate was checked. Three primary results were obtained: (i) the visible light response was not due to nitrogen doping but to other impurities in the metal and to the surface of tantalum oxide/tantalum plate, (ii) the thickness of tantalum oxide film was an important factor influencing the energy conversion efficiency, and (iii) formic acid was successfully generated from carbon dioxide. In future experiments, the ability of tantalum oxide/tantalum plate to reduce carbon dioxide efficiently using sunlight will be examined.
The energy conversion efficiency will be improved and the material will be applied as a practical solution to environmental problems.
关键词
tantalum oxide;tantalum plate;visible light;carbon dioxide;high energy conversion efficiency
有方独家点评
该课题基于氧化钽催化二氧化碳的还原反应,解释了氧化钽对可见光的响应现象。研究通过钽板热处理、光辐射下测量电压和电流、使用可见光检查波长依赖性和使用恒电位仪测量导电的电势四个实验,解释了光响应现象的机理,并根据其机理制造出具有高能量转换效率的氧化钽/钽板。氧化钽/钽板的使用将提高能量的转化效率,并且可以该材料将作为环境问题的实用解决方案。
本期文章福利
2017 ISEF 获奖论文
( Chemistry )
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MA Regional Fair三等奖(晋级State)
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MI Regional Fair 一等奖(直接晋级ISEF总决赛)
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State Fair Top6(晋级ISEF总决赛)
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导师:加州大学洛杉矶分校 ( UCLA )
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